Spectrophotometric and Selective Nickel(II) Detection by Dimethylglyoxime as an Optical Chemical

Authors

  • Rashd M. EL-Ferjani Department of Chemistry, Faculty of Science, University of Benghazi
  • Ayah O. Abouligheeb Department of Chemistry, Faculty of Arts and Sciences Al-Abyar Branch, University of Benghazi
  • Marwa F. Alturshani Department of Chemistry, Faculty of Arts and Sciences Ghemines Branch, University of Benghazi
  • Mawda F. Iswery Department of Chemistry, Faculty of Arts and Sciences Ghemines Branch, University of Benghazi
  • Esraa F. Alzaedy Department of Chemistry, Faculty of Arts and Sciences Ghemines Branch, University of Benghazi
  • Hiyam Abdallah Department of Chemistry, Faculty of Arts and Sciences Al-Abyar Branch, University of Benghazi
  • Abdulfatah Yahya Department of Chemistry, Faculty of Science, University of Benghazi

DOI:

https://doi.org/10.37375/p28van79

Keywords:

Solution structure; Optical chemical sensor; Spectrophotometric; Selective

Abstract

Owing to their remarkable selectivity, sensitivity, and rapid detection capabilities, optical sensors have garnered significant scholarly attention for the identification of various metal ions. Given its toxicological implications and pervasive application across numerous industrial processes, nickel(II) has become a focal point of research among metal ions. In recent years, a variety of optical chemical sensors exhibiting exceptional sensitivity and selectivity have been developed specifically for the detection of Ni(II). In the present study, a dimethylglyoxime(DMG) optical chemical sensor is employed to quantify trace amounts of Ni(II) using spectrophotometric techniques under controlled pH conditions. resulting in well-defined Ni(II) complex with characteristic absorption maxima at 568 nm. Optical sensing showed excellent linearity between absorbance and Ni(II) concentration, with correlation coefficients (R2) of 0.9952. and limits of detection (LOD) of 1×10-4. DMG has emerged as an effective effective reagent for the detection of Ni(II) ions in a range of aqueous samples functioning as an optical chemical sensor.

References

Adams, R., & Kamm, O. (1918). Organic chemical reagents. I. Dimethylglyoxime. Journal of the American Chemical Society, 40(8), 1281–1289.

Aksuner, N., Henden, E., Yilmaz, I., & Cukurovali, A. (2012). A novel optical chemical sensor for the determination of nickel (II) based on fluorescence quenching of newly synthesized thiazolo-triazol derivative and application to real samples. Sensors and Actuators B: Chemical, 166, 269–274.

Cardoso, W. S., Dias, V. L., Costa, W. M., de Araujo Rodrigues, I., Marques, E. P., Sousa, A. G., … Marques, A. L. (2009). Nickel-dimethylglyoxime complex modified graphite and carbon paste electrodes: Preparation and catalytic activity towards methanol/ethanol oxidation. Journal of Applied Electrochemistry, 39(1), 55–64.

Eprilia, N., Sanjaya, A. R., Pramadewandaru, R. K., Pertiwi, T. A., Putri, Y. M., Rahmawati, I., … Ivandini, T. A. (2024). Preparation of nickel foam modified by multiwalled hollow spheres of NiCo₂O₄ as a promising non-enzymatic glucose sensor. RSC Advances, 14(15), 10768–10775.

Ferancová, A., Hattuniemi, M. K., Sesay, A. M., Räty, J. P., & Virtanen, V. T. (2017). Complexation of Ni (II) by dimethylglyoxime for rapid removal and monitoring of Ni (II) in water. Mine Water and the Environment, 36(2), 273–282.

Huheey, J. E., Keiter, E. A., Keiter, R. L., & Medhi, O. K. (2006). Inorganic chemistry: Principles of structure and reactivity. Pearson Education India.

Jain, A. K., Gupta, V. K., Singh, R. D., Khurana, U., & Singh, L. P. (1997). Nickel (II)-selective sensors based on heterogeneous membranes of macrocyclic compounds. Sensors and Actuators B: Chemical, 40(1), 15–20.

Jiang, J., Gou, C., Luo, J., Yi, C., & Liu, X. (2012). A novel highly selective colorimetric sensor for Ni (II) ion using coumarin derivatives. Inorganic Chemistry Communications, 15, 12–15.

Li, J. J., Hou, C. J., Huo, D. Q., Shen, C. H., Luo, X. G., Fa, H. B., … Zhou, J. (2017). Detection of trace nickel ions with a colorimetric sensor based on indicator displacement mechanism. Sensors and Actuators B: Chemical, 241, 1294–1302.

Morgan, E. (1990). Vogel’s textbook of practical organic chemistry (5th ed.). Endeavour.

Shi, W., He, S., Wei, M., Evans, D. G., & Duan, X. (2010). Optical pH sensor with rapid response based on a fluorescein‐intercalated layered double hydroxide. Advanced Functional Materials, 20(22), 3856–3863.

Singh, L. P., & Bhatnagar, J. M. (2003). PVC based selective sensors for Ni²⁺ ions using carboxylated and methylated porphine. Sensors, 3(9), 393–403.

Upstone, S. L. (2006). Ultraviolet/visible light absorption spectrophotometry and fluorescence spectroscopy in clinical chemistry. In Encyclopedia of Analytical Chemistry: Applications, theory and instrumentation (pp. 1–25).

Yari, A., Azizi, S., & Kakanejadifard, A. (2006). An electrochemical Ni (II)-selective sensor based on a newly synthesized dioxime derivative as a neutral ionophore. Sensors and Actuators B: Chemical, 119(1), 167–173.

Downloads

Published

17-04-2026

How to Cite

Spectrophotometric and Selective Nickel(II) Detection by Dimethylglyoxime as an Optical Chemical. (2026). Scientific Journal for Faculty of Science-Sirte University, 6(1), 101-106. https://doi.org/10.37375/p28van79

Similar Articles

11-20 of 52

You may also start an advanced similarity search for this article.