Sustainable Use of Silk Vine Roots(S-VPR) as Low Cost Adsorbent for the Removal of Methylene Blue Dye from Its Aqueous Solution

Authors

  • Rajoan Mohammed Chemistry Department, Faculty of Science, Sirte University, Libya.
  • Abdussalam Salhin Mohamed Department of chemistry, Faculty of Science, Sirte University, Sirte, Libya
  • Ashraf M. Abusenaina Department of chemistry, Faculty of Science, Sirte University, Sirte, Libya
  • Fatima Abullrhman Khalifa Department of chemistry, Faculty of Science, Sirte University, Sirte, Libya
  • Aze Salem Mohamed Department of chemistry, Faculty of Science, Sirte University, Sirte, Libya

DOI:

https://doi.org/10.37375/sjfssu.v4i2.2899

Keywords:

Adsorption, Methylene blue, Silkvine plant

Abstract

This study examines the adsorption of methylene blue dye from an aqueous solution using silk vine roots derived from dairy powder. The adsorbent material was utilized in its natural state, without any chemical or physical treatment. The adsorption process was conducted under different conditions, including pH, adsorbent weight, initial dye concentration, and contact time at room temperature. The adsorption capacity exhibited an increase (49.9 mg/g), whereas the adsorbent weight and initial concentration increased until equilibrium was reached within 20 minutes. The adsorption process followed second-order kinetics and displayed compatibility with the Freundlich isotherm coefficient. It was determined to be a multilayer, heterogeneous adsorption process with a maximum adsorption capacity value (qe max 49.9 mg/g). Based on the results, it can be confirmed that wild dairy (silk vine) is capable of effectively adsorbing pollutants, such as the blue methylene dye.

References

Abechi, S., Gimba, C., Uziaru, A., & Ndukwe, I. (2010). Comparative studies on adsorption of methylene blue (MB) by sawdust and walnut shells carbon coated with ZnO. Science World Journal, 1(1). https://doi.org/10.4314 /swj .v1i1 .51696

Adachi, A., Ouadrhiri, F. E., Manssouri, I. E., Moussaoui, F., Bourachdi, S. E., & Lahkimi, A. (2023). Removal of dyes by adsorption process using date pits as environmentally friendly material. Ecological Engineering & Environmental Technology, 24(8), 181–193.https://doi.org/10.12912/27197050/171494

Ali, I. (2010). The Quest for Active Carbon Adsorbent Substitutes: Inexpensive Adsorbents for Toxic Metal Ions Removal from Wastewater. Separation and Purification Reviews, 39(3–4), 95–171. https://doi.org/10. 1080/15422119.20 10. 527 802.

Amalina, I. F., Haziq, J. M., Syukor, A. R. A., Rashid, A. H. M., & Izzati, K. a. N. (2020). Formulation of Capra hircus feed to utilize artocarpus heterophyllus leaves and palm acid oil (PAO). IOP Conference Series Materials Science and Engineering, 736(2), 022016. https://doi.org/10.1088/1757-899x/736/2/022016

Azhar, S. S., Liew, A. G., Suhardy, D., Hafiz, K. F., & Hatim, M. I. (2005). Dye Removal from Aqueous Solution by using Adsorption on Treated Sugarcane Bagasse. American Journal of Applied Sciences, 2(11), 1499–1503. https://doi.org/10.3844/ajassp.2005.1499.1503

Baek, M., Ijagbemi, C. O., O, S., & Kim, D. (2010). Removal of Malachite Green from aqueous solution using degreased coffee bean. Journal of Hazardous Materials, 176(1–3), 820–828. https://doi.org/10.1016 /j.jhazmat. 2009. 11.110

Bukallah, S., Rauf, M., & Alali, S. (2007). Removal of Methylene Blue from aqueous solution by adsorption on sand. Dyes and Pigments, 74(1), 85–87. https://doi.org/10.10 16 /j.dyepig.2006.01.016

Chequer, F. M. D., De Oliveira, G. a. R., Ferraz, E. R. A., Carvalho, J., Zanoni, M. V. B., & De Oliveir, D. P. (2013). Textile dyes: Dyeing process and environmental impact. In InTech eBooks. https://doi.org/10.5772/53659

Chieng, H. I., Zehra, T., Lim, L. B. L., Priyantha, N., & Tennakoon, D. T. B. (2014). Sorption characteristics of peat of Brunei Darussalam IV: equilibrium, thermodynamics and kinetics of adsorption of methylene blue and malachite green dyes from aqueous solution. Environmental Earth Sciences, 72(7), 2263–2277. https://doi.org/10.1007/s12665-014-3135-7

Da Silva, L. G., Ruggiero, R., De M Gontijo, P., Pinto, R. B., Royer, B., Lima, E. C., Fernandes, T. H., & Calvete, T. (2011). Adsorption of Brilliant Red 2BE dye from water solutions by a chemically modified sugarcane bagasse lignin. Chemical Engineering Journal, 168(2), 620–628. https://doi.org/10.1016/j.cej.2011.01.040

Ekpete O.A.and Horsfall M. JNR ., (2011). Preparation and characterization of activated carbon from fluted pumpkin (Telfairia occidentalis Hook. F) seed shell. Asian journal of natural and applied scien Research Journal of Chemical Sciencesces, Vol. 1(3) June p 10-16.

Erhayem, M., Gaith, R., Otman, O. E., & Frage, M. U. (2020). Adsorption, Kinetic and Thermodynamic Study for Removal of Nickel Ions by Activated Carbon from Palm Kernel. Iranica Journal of Energy and Environment, 11(4). https://doi.org/10.5829 /ijee.2020 .11. 0

Faraja, M,, and * Erhayemam, M., and M,Ragwan.,(2019). Kinetics and Thermodyn amic Study for Adsorption of Methylene Blue onto Mulberry Tree ( Morus nigra L) Roots Powder, JOPAS Vol.18 No. 4 . ISSN 2521-92004.12.

Foo, K., & Hameed, B. (2010). Decontamination of textile wastewater via TiO2/activated carbon composite materials. Advances in Colloid and Interface Science, 159(2), 130–143. https://doi.org/10.10 16/j.cis .2010.06.002

Ham daoui, O. and M. Chiha, (2007). Removal of Methylene Blue from Aqueous Solutions by Wheat Bran. Acta Chimica Slovenica, 54(2) 407–418

Hameed, B. H., Din, A. T. M., & Ahmad, A. L. (2007). Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies. Journal of Hazardous Materials, 141(3), 819–825. https://doi.org/10 .1016/j.jhazmat.2006.07.049

Han, R., Zou, W., Yu, W., Cheng, S., Wang, Y., & Shi, J. (2007). Biosorption of methylene blue from aqueous solution by fallen phoenix tree’s leaves. Journal of Hazardous Materials, 141(1), 156–162. https://doi.org/1 0.1016/j. jhazmat .2006.06.107

Hashem, A., & Elhmmali, M. M. (2006). Modification of Sodium Alginate for the Removal of Cd(II) from Aqueous Solutions. Polymer-PlasticsTechnology and Engineer ing, 45(6), 707–712. https://doi.org /10. 1080 /03602550600609648

Hill, I. R. (1979). Book Review: Introduction to Soil Microbiology, 2nd edition. Outlook on Agriculture, 10(2), 106. https://doi.org/10.1 177 /003072707901000208

Holkar, C. R., Jadhav, A. J., Pinjari, D. V., Mahamuni, N. M., & Pandit, A. B. (2016). A critical review on textile wastewater treatments: Possible approaches. Journal of Environmental Management, 182, 351–366. https://doi.org/10.1016/j.jenvman.2016.07.090

Papagiannaki, D., Belay, M. H., Gonçalves, N. P., Robotti, E., Bianco-Prevot, A., Binetti, R., & Calza, P. (2022). From monitoring to treatment, how to improve water quality: The pharmaceuticals case. Chemical Engineering Journal Advances, 10, 100245. https://doi.org/10.1016/j.ceja.2022.100245

RAGHUVANSHI, S. P. (2004). KINETICS STUDY OF METHYLENE BLUE DYE BIOADSORPTION ON BAGGASE. Applied Ecology and Environmental Research, 2(2), 35–43. https://doi.org/10.15666/aeer/03035043Selen, V., Güler, Ö., Özer, D., & Evin, E. (2016). Synthesized multi-walled carbon nanotubes as a potential adsorbent for the removal of methylene blue dye: kinetics, isotherms, and thermodynamics. Desalination and Water Treatment, 57(19), 8826–8838. https://doi.org/10.1080/19443994.2015.1025851

Sharma*, Y. C., B. Singh and Uma., (2009) . Fast removal of malachite green by adsorption on rice husk activated carbon. The Open Environmental Pollution & Toxicology Journal,. 1(1): p. 74-78. 1876-3979/09 DOI: 10.2174/ 1876397900901010074]

Suteu, D., & Malutan, T. (2012). Industrial Cellolignin Wastes as Adsorbent for Removal of Methylene Blue Dye from Aqueous Solutions. BioResources, 8(1). https://doi.org/ 10.1537 6/biores.8.1.427-446

Verma, A. K., Dash, R. R., & Bhunia, P. (2012). A review on chemical coagulation/ flocculation technologies for removal of colour from textile wastewaters. Journal of Environmental Management, 93(1), 154–168. https://doi.org/10.1016/j .jenvman. 201 1.09. 012

Wang, L., Zhang, J., & Wang, A. (2011). Fast removal of methylene blue from aqueous solution by adsorption onto chitosan-g-poly (acrylic acid) /attapulgite composite. Desali nation, 266(1–3), 33–39. https://doi.or g/10.1 016 / j.desal.2010.07.065

Zhang, H., Tang, Y., Liu, X., Ke, Z., Su, X., Cai, D., Wang, X., Liu, Y., Huang, Q., & Yu, Z. (2011). Improved adsorptive capacity of pine wood decayed by fungi Poria cocos for removal of malachite green from aqueous solutions. Desalination, 274(1–3), 97–104. https://doi.org/10.1016/j.desal.2011.01.077

Downloads

Published

2024-10-26

How to Cite

Mohammed, R., Mohamed, A. S., Abusenaina , A. M., Khalifa, F. A., & Mohamed, A. S. (2024). Sustainable Use of Silk Vine Roots(S-VPR) as Low Cost Adsorbent for the Removal of Methylene Blue Dye from Its Aqueous Solution: . Scientific Journal for Faculty of Science-Sirte University, 4(2), 86–93. https://doi.org/10.37375/sjfssu.v4i2.2899