Maleic Acid Separation from Aqueous Solutions Utilizing Amberlite LA-2
DOI:
https://doi.org/10.37375/sjfssu.v3i2.1387Keywords:
Keywords: Maleic acid, Amberlite LA-2, distribution coefficients (KD), loading coefficients (Z), extraction efficiency (%E)Abstract
This study investigates the potential uses of Amberlite LA-2 for the recovery of maleic acid from an aqueous solution. The effects of the initial concentration of maleic acid and Amberlite LA-2, pH, contact time, and temperature were determined and evaluated. The experimental results of extraction were used to calculate the distribution coefficient (KD), and extraction efficiency (E%). The results show that the extraction efficiency increased with the increase in the initial concentration of maleic acid, where the percentage increased from 92.65% to 99.01% when the concentration of acid was increased from 0.01 to 0.075 N. The percentage of maleic acid extraction was also increased from 85.3 to 98% with the increase in the concentration of Amberlite LA-2 from 0.044 to 0.22 M. The acid extracted from the aqueous phase to the organic phase increases with time, and the quantitative transfer of maleic acid occurred after 60 minutes. At a concentration of 0.05 M, the percentage of extracted acid was observed to increase from 98.8% to 99.95% when temperature was increased from 25 to 40 oC. The highest percentage of acid extraction was recorded at pH=3, which is (90.3%). The maximum loading modulus reached a value of 1.6877 at a concentration of 0.044 M of the secondary amine.
References
AL-abbasi, A., Alammarwy, A., & Abdulljaoad, S. (2022). Removal of Methyl Orange Dye from Aqueous Solutions using Amberlite LA-2 as an Extractant. Journal of Pure and Applied Sciences, 21(2), 55-60
AL-abbasi, A., Ehwedi, A., Ahmida, K., and Saleh,F., . (2023). Congo Red Removal From Aqueous Solutions by Ion ExchangerAmberliteLA-2. Al-Mukhtar Journal of Sciences, 38(1), 9–18. doi: https://doi.org/10.54172/mjsc.v38i1.996
Al-abbasi, A., Emmhemad, H., Suliman, H. (2022). Liquid-Liquid Extraction of Tartaric Acid from Aqueous Solutions by Amberlite LA-2 as Liquid Ion Exchanger. Libyan Journal of Ecological & Environmental Sciences and Technology, 4(2), 5-12. Retrieved from https://www.srcest.org.ly/jou/paper/1672454126382.pdf
Al-abbasi, A., & Kassim, M. (2011). 1-Ethyl-1-methyl-3-(2-nitrobenzoyl)thiourea. Acta Crystallographica Section E, 67(7), o1840. doi:doi:10.1107/S1600536811024652
Al-abbasi, A., Tan, S., & Kassim, M. (2010). 1-Benzoyl-3-(4-hydroxyphenyl)thiourea. Acta Crystallographica Section E, 66(12), o3181. doi:doi:10.1107/S1600536810045988
Aşçı, Y. S., and Ismail, I. (2009). Extraction of Glycolic Acid from Aqueous Solutions by Amberlite LA-2 in Different Diluent Solvents. Journal of Chemical & Engineering Data, 54(10), 2791-2794. doi:10.1021/je800722a
Aşçı, Y. S., & İnci, İ. (2009). Extraction equilibria of propionic acid from aqueous solutions by Amberlite LA-2 in diluent solvents. Chemical Engineering Journal, 155(3), 784-788. doi:https://doi.org/10.1016/j.cej.2009.09.024
Aşçı, Y. S., & İncı̇, İ. (2009). Extraction of Glycolic Acid from Aqueous Solutions by Amberlite LA-2 in Different Diluent Solvents. Journal of Chemical & Engineering Data, 54(10), 2791-2794. doi:10.1021/je800722a
Belkher, N., A. Al-abbas and M. Zidan. (2019). Potentiometric Studies on Stability Constant of the Complexes of Some Essential Transition Metal Ions with L-Valine. Journal of Pure & Applied Sciences, 18(3), 59-63.
Blumberg, R. (1988). Liquid-liquid Extraction: Academic Press.
Dethe, M. J., Marathe, K. V., & Gaikar, V. G. (2006). Adsorption of Lactic Acid on Weak Base Polymeric Resins. Separation Science and Technology, 41(13), 2947-2971. doi:10.1080/01496390600851384
Khalifa, S., AL-abbassi, A., Suliman, M. (2018). Adsorption and Corrosion Inhibition of Mild Steel in Acidic Media by Expired Pharmaceutical Drug. Journal of Pure & Applied Sciences, 17, 1-6.
Khopkar, S. M. (2007). Solvent Extraction: Separation of Elements with Liquid Ion Exchangers: New Age International, Publishers.
Kloetzer, L., Ilica, R., Cascaval, D., Galaction, A. (2019). Separation of fumaric acid by amine extraction without and with 1-octanol as phase modifier. Separation and Purification Technology, 227, 115724. doi:https://doi.org/10.1016/j.seppur.2019.115724
Kunin, R., & Winger, A. G. (1962). Liquid Ion-Exchange Technology. Angewandte Chemie International Edition in English, 1(3), 149-155. doi:https://doi.org/10.1002/anie.196201491
Lo, T. C., Baird, M., & Hanson, C. (1991). Handbook of Solvent Extraction.
Nasef, M., Ujang, Z. (2012). Introduction to Ion Exchange Processes. In M. Inamuddin Luqman (Ed.), Ion Exchange Technology I: Theory and Materials (pp. 1-39). Dordrecht: Springer Netherlands.
Raynie, D. E. (2000). EXTRACTION. In I. D. Wilson (Ed.), Encyclopedia of Separation Science (pp. 118-128). Oxford: Academic Press.
Ricci, L. (1980). Separation Techniques: Liquid-liquid systems: Chemical Engineering.
Smith, E. L., & Page, J. E. (1948). The acid-binding properties of long-chain aliphatic amines. Journal of the Society of Chemical Industry, 67(2), 48-51. doi:https://doi.org/10.1002/jctb.5000670203
urali, N. S., K.; Ahring, B.K. . , 3, 22. (2017 ). Biochemical Production and Separation of Carboxylic Acids for Biorefinery Applications. Fermentation, 3, 1-25.
Uslu, H. (2016). Extraction equilibria of 2,4,6-Trinitrophenol by (amberlite LA2 + ester) solvents. Fluid Phase Equilibria, 427, 175-179. doi:https://doi.org/10.1016/j.fluid.2016.07.002
Uslu, H., and , & Kırbaşlar, I. (2010). Solvent effects on the extraction of malic acid from aqueous solution by secondary amine extractant. Separation and Purification Technology, 71(1), 22-29. doi:https://doi.org/10.1016/j.seppur.2009.10.006
Uslu, H., Bayat, C., Gökmen, S., & Yorulmaz, Y. (2009). Reactive Extraction of Formic Acid by Amberlite LA-2 Extractant. Journal of Chemical & Engineering Data, 54(1), 48-53. doi:10.1021/je8005584
Uslu, H., Baykal, E., Gök, A., Kırbaşlar, Ş. İ., & Santos, D. (2020). Study on Oxalic Acid Extraction by Tripropylamine: Equilibrium and Computational COSMO-SAC Analysis. Journal of Chemical & Engineering Data, 65(9), 4347-4353. doi:10.1021/acs.jced.9b01150
Uslu, H., Datta, D., Santos, D., & Öztürk, M. (2019). Separation of Levulinic Acid Using Polymeric Resin, Amberlite IRA-67. Journal of Chemical & Engineering Data, 64(7), 3044-3049. doi:10.1021/acs.jced.9b00137
Wennersten, R. (1983). Extraction of Carboxylic Acid from Fermentation Broth Using Solution of Tertiary Amine. Journal of Chemical Technology & Biotechnology, 33-B, 85-94.
Werner, G. (1974). The use of liquid ion exchangers in extraction chromatography. Journal of Chromatography A, 102, 69-73. doi:https://doi.org/10.1016/S0021-9673(01)85428-5
Wiley. Maleic Anhydride, Maleic Acid, and Fumaric Acid. In Van Nostrand's Scientific Encyclopedia (pp. 1-5).
Wojcieszak, R., Santarelli, F., Paul, S., Dumeignil, F., Cavani, F., & Gonçalves, R. V. (2015). Recent developments in maleic acid synthesis from bio-based chemicals. Sustainable Chemical Processes, 3(1), 9. doi:10.1186/s40508-015-0034-5
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Scientific Journal for Faculty of Science-Sirte University
This work is licensed under a Creative Commons Attribution 4.0 International License.