Growth Mechanism, Kinetics and Thermodynamics Evaluation of Silver Nanoparticles Prepared by Aqueous Seeds Extract of Ziziphus Spina-Christi

Authors

  • Abudelrhman Faraj Chemistry Department, Faculty of Science, Sebha University, Libya
  • Mohamed Erhayem Chemistry Department, Faculty of Science, Sebha University, Libya
  • Mansour Faraj Chemistry Department, Faculty of Science, Sebha University, Libya

DOI:

https://doi.org/10.37375/susj.v13i2.2499

Keywords:

growth mechanism, Kinetic, silver nanoparticles, Thermodynamic and Ziziphus Spina-Christi, seeds

Abstract

in the present study, silver nanoparticles, Ag-NPs have been prepared by a Aqueous Seeds Extract of Ziziphus Spina-Christi as reducing agent and a solution of silver nitrate (AgNO3). From poly nuclear growth rate model, the rate of growth was found to be equals 0.0011 nm/min. Different morphologies of silver colloids could be obtained using different temperature. The reduction kinetic of Ag+ was followed the second order model. Also, the synthesis of Ag-NPs was endothermic reaction and spontaneous at medium and high temperature while non spontaneous at low temperature. Gibbs free energy of formation was not constant and was changed with radios of Ag-NPs

References

Basalius, H., Mani, A., Michael, A., Mary, S. M., Lenin, M., Chelliah, P., . . . Islam, M. A. J. A. N. (2023). Green synthesis of nano-silver using Syzygium samarangense flower extract for multifaceted applications in biomedical and photocatalytic degradation of methylene blue. 13(6), 3735-3747.

Cao, G., & Wang, Y. (2011). Nanostructures And Nanomaterials: Synthesis, Properties, And Applications (2nd Edition): World Scientific Publishing Company.

Hu, S., & Hsieh, Y.-L. J. I. j. o. b. m. (2016). Silver nanoparticle synthesis using lignin as reducing and capping agents: A kinetic and mechanistic study. 82, 856-862.

Kokila, T., Ramesh, P., & Geetha, D. J. A. N. (2015). Biosynthesis of silver nanoparticles from Cavendish banana peel extract and its antibacterial and free radical scavenging assay: a novel biological approach. 5(8), 911-920.

Masoodiyeh, F., Karimi-Sabet, J., Khanchi, A., & Mozdianfard, M. J. P. T. (2015). Zirconia nanoparticle synthesis in sub and supercritical water—particle morphology and chemical equilibria. 269, 461-469.

Skіba, М., Pivovarov, О., Makarova, A., & Vorobyova, V. J. В.-Е. ж. п. т. (2018). Plasmochemical preparation of silver nanoparticles: thermodynamics and kinetics analysis of the process. (2 (6)), 4-9.

Downloads

Published

2023-12-17