Physicochemical, Morphological, and Thermal Characterization of Selected Clay Samples from Southern Libya

Authors

  • Aishah Ramadan Mohamed Environmental Science Department, Faculty of Environment and Natural Resource, Wadi Alshatti University; Libyan Center for Studies and Research in Environmental Science and Technology

DOI:

https://doi.org/10.37375/susj.v16i1.4138

Keywords:

clay characterization, southern Libya, physicochemical properties, Munsell color, drying curve, shrinkage

Abstract

Eight clay samples collected from southern Libya were characterized using descriptive observation, light-microscope examination, Munsell color estimation, and selected physicochemical tests. The samples showed clear differences in color, texture, particle appearance, moisture content, pH, electrical conductivity, particle density, shrinkage behavior, exchangeable cations, and water-extractable phosphorus. Moisture contents were low in all samples, ranging from 0.09-1.06%, which indicates that the samples were close to air-dry condition before testing. The pH values ranged from 5.49-7.31, indicating slightly acidic to near-neutral conditions. Electrical conductivity ranged from 0.20-5.27 dS.m−1, with Sample 2 showing the highest value, most likely because of a higher concentration of soluble salts. Particle density ranged from 1.88-2.31 g.cm−3, while the shrinkage/expansion coefficient ranged from 1.81-6.59%. Water-extractable phosphorus varied widely from 0.97-87.6 mg.Kg−1, indicating substantial differences in soluble phosphorus among the samples. Drying-curve data showed limited mass loss below 200 °C, followed by more pronounced losses at higher temperatures. By 800 °C, the total mass loss ranged from approximately 8.8-15.7%, with Sample 8 showing the highest total loss. These results provide an initial basis for evaluating southern Libyan clay as a local natural resource, but further mineralogical and application-specific testing is required before industrial or environmental use can be recommended

References

Al-Ani, T., & Sarapää, O. (2008). Clay and clay mineralogy: Physical-chemical properties and industrial uses. Geological Survey of Finland, Report M19/3232/2008/41.

Barrow, N. J., & Hartemink, A. E. (2023). The effects of pH on nutrient availability depend on both soils and plants. Plant and Soil, 487(1–2), 21–37. https://doi.org/10.1007/s11104-023-05960-5.

Bergaya, F., & Lagaly, G. (Eds.). (2013). Handbook of clay science (2nd ed., Developments in Clay Science, Vol. 5). Elsevier.

Brady, N. C., & Weil, R. R. (2017). The nature and properties of soils (15th ed.). Pearson.

Cáceres, J. R., Pineda-Rodríguez, J. R., & Rojas-Suárez, J. P. (2021). Analysis of the ratio between the plasticity of clay and the expansion capacity by changes in humidity and temperature. Journal of Physics: Conference Series, 2139(1), 012010. https://doi.org/10.1088/1742-6596/2139/1/012010.

Cerato, A. B., & Lutenegger, A. J. (2006). Shrinkage of clays. In Unsaturated Soils 2006 (GSP 147, pp. 1097–1108). American Society of Civil Engineers. https://doi.org/10.1061/40802(189)89.

Cheng, S., Jiu, S., & Li, H. (2021). Kinetics of dehydroxylation and decarburization of coal series kaolinite during calcination: A novel kinetic method based on gaseous products. Materials, 14(6), 1493. https://doi.org/10.3390/ma14061493.

Chima, O., Nwoye, C., & Nnuka, E. (2017). Enhancement of refractory properties of blended clay with groundnut shell and rice husk additives. American Journal of Engineering Research, 6(6), 218–226.

Corwin, D. L., & Yemoto, K. (2019). Measurement of soil salinity: Electrical conductivity and total dissolved solids. Soil Science Society of America Journal, 83(1), 1–2. https://doi.org/10.2136/sssaj2018.06.0221.

Derkowski, A., & Kuligiewicz, A. (2023). Thermal analysis and thermal reactions of smectites: A review of methodology, mechanisms, and kinetics. Clays and Clay Minerals, 70(6), 946–972. https://doi.org/10.1007/s42860-023-00222-y

Dhahri, F., Alashkham, E., & Sofe, M. (2024). Opportunities and challenges for the Libyan geological resource’s development: An overview. Mineral Economics, 37(3), 719–723. https://doi.org/10.1007/s13563-023-00385-z.

Elssaidi, M. A., & Mohamed, A. R. (2020). Soil and water physical & chemical properties of Tragen Sabkha area, southwest Libya. Al-Mukhtar Journal of Sciences, 35(1), 46–59.https://doi.org/10.54172/mjsc.v35i1.63.

Escadafal, R., Girard, M. C., & Courault, D. (1989). Munsell soil color and soil reflectance in the visible spectral bands of Landsat MSS and TM data. Remote Sensing of Environment, 27(1), 37–46. https://doi.org/10.1016/0034-4257(89)90035-7

FAO. (1985). Irrigation water management: Training manual No. 1 – Salinity and sodicity. Food and Agriculture Organization of the United Nations. https://www.fao.org

FAO. (2001). Lecture notes on the major soils of the world. Food and Agriculture Organization of the United Nations.https://www.fao.org/4/y1899e/y1899e00.htm

FAO. (2018). Salt-affected soils: Management and rehabilitation. Food and Agriculture Organization of the United Nations. https://www.fao.org

Hanein, T., Thienel, K.-C., Zunino, F., et al. (2022). Clay calcination technology: State-of-the-art review by the RILEM TC 282-CCL. Materials and Structures, 55, 3. https://doi.org/10.1617/s11527-021-01807-6

Hardy, D. H., Tucker, M. R., & Stokes, C. E. (2013). Understanding the soil test report. North Carolina Department of Agriculture & Consumer Services, Agronomic Division.

Horneck, D. A., Sullivan, D. M., Owen, J. S., & Hart, J. M. (2011). Soil test interpretation guide (EC 1478). Oregon State University Extension Service.

Huang, J., Liu, Z., Cui, Y., Yuan, Q., & Deng, D. (2024). Half-decomposition of salt-bearing dolomite. RSC Advances, 14, 11358–11367. https://doi.org/10.1039/D4RA01341G.

Jenny, H. (1994). Factors of soil formation: A system of quantitative pedology. Dover Publications.

Kumari, N., & Mohan, C. (2021). Basics of clay minerals and their characteristic properties. In G. M. do Nascimento (Ed.), Clay and Clay Minerals. IntechOpen.https://doi.org/10.5772/intechopen.97672.

Lok, M. M. T., Tan, N. P., Tee, Y. K., & Teh, C. B. S. (2024). Review of the innovations and challenges in developing rapid colorimetry and turbidity NPK soil test kits for commercial soil nutrient analysis. Pertanika Journal of Tropical Agricultural Science, 47(4), 1405–1428. https://doi.org/10.47836/pjtas.47.4.21.

Malizia, J. P., & Shakoor, A. (2018). Effect of water content and density on strength and deformation behavior of clay soils. Engineering Geology, 244, 125–131. https://doi.org/10.1016/j.enggeo.2018.07.028.

McAuliffe, J. R., McFadden, L. D., Persico, L. P., & Rittenour, T. M. (2022). Climate and vegetation change, hillslope soil erosion, and the complex nature of late Quaternary environmental transitions, eastern Mojave Desert, USA. Quaternary, 5(4), 43. https://doi.org/10.3390/quat5040043.

McBratney, A. B., Field, D. J., & Koch, A. (2014). The dimensions of soil security. Geoderma, 213, 203–213. https://doi.org/10.1016/j.geoderma.2013.08.013

Mogashane, T. M., Mapazi, O., Motlatle, M. A., Mokoena, L., & Tshilongo, J. (2025). A review of recent developments in analytical methods for determination of phosphorus from environmental samples. Molecules, 30(5), 1001. https://doi.org/10.3390/molecules30051001.

Munsell Color Company. (1994). Munsell soil color charts. Macbeth Division of Kollmorgen Instruments Corporation.

Peila, D., Picchio, A., Martinelli, D., & Dal Negro, E. (2016). Laboratory tests on soil conditioning of clayey soil. Acta Geotechnica, 11(5), 1061–1074. https://doi.org/10.1007/s11440-015-0406-8.

Plevová, E., & Vaculíková, L. (2024). Thermal behavior of ceramic bodies based on fly ash and smectites. Minerals, 14(4), 334. https://doi.org/10.3390/min14040334

Qi, Y., & Wu, Y. (2022). Electrical conductivity of clayey rocks and soils: A non-linear model. Geophysical Research Letters, 49(10), e2021GL097408. https://doi.org/10.1029/2021GL097408

Rochow, T. G., & Tucker, P. A. (1994). Introduction to microscopy by means of light, electrons, X rays, or acoustics. Springer. https://doi.org/10.1007/978-1-4899-1513-9

Schneider, S. C., & Skarbøvik, E. (2022). Ecological status assessment of clay rivers with naturally enhanced water phosphorus concentrations. Environmental Advances, 9, 100279. https://doi.org/10.1016/j.envadv.2022.100279

Shukla, A., Panchal, H., Mishra, M., Patel, P. R., Srivastava, H. S., Patel, P., & Shukla, A. K. (2014). Soil moisture estimation using gravimetric technique and FDR probe technique: A comparative analysis. American International Journal of Research in Formal, Applied & Natural Sciences, 8(1), 89–92.

Sirisathitkul, Y., & Sirisathitkul, C. (2025). Decoding soil color: Origins, influences, and methods of analysis. AgriEngineering, 7(3), 58. https://doi.org/10.3390/agriengineering7030058

Soinne, H., Keskinen, R., Tähtikarhu, M., Kuva, J., & Hyväluoma, J. (2023). Effects of organic carbon and clay contents on structure-related properties of arable soils with high clay content. European Journal of Soil Science, 74(5), e13424. https://doi.org/10.1111/ejss.13424.

Sumner, M. E. (2000). Handbook of soil science. CRC Press.

Uddin, M. K. (2017). A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal, 308, 438–462. https://doi.org/10.1016/j.cej.2016.09.029.

Wang, T., Yu, L., Wang, Z., Yang, C., Dong, F., Yang, D., Xi, H., Sun, Z., Bol, R., Awais, M., Yang, L., & Fu, H. (2025). Effect of simulated acidification on soil properties and plant nutrient uptake of eggplant in greenhouse. Frontiers in Plant Science, 16, 1558458. https://doi.org/10.3389/fpls.2025.1558458.

Wersin, P., Emmerich, K., & Kulik, D. (2024). Rehydroxylation of calcined swellable clay minerals at ambient conditions. Applied Clay Science, 247, 107113. https://doi.org/10.1016/j.clay.2023.107113.

Wuddivira, M. N., Robinson, D. A., Lebron, I., Bréchet, L., Atwell, M., De Caires, S., Atkinson, M., & Tuller, M. (2012). Estimation of soil clay content from hygroscopic water content measurements. Soil Science Society of America Journal, 76(5), 1529–1535. https://doi.org/10.2136/sssaj2012.0034.

Yariv, S. (1991). Differential thermal analysis (DTA) of organo-clay complexes. In W. Smykatz-Kloss & S. S. J. Warne (Eds.), Thermal Analysis in the Geosciences (Lecture Notes in Earth Sciences, Vol. 38, pp. 328–351). Springer. https://doi.org/10.1007/BFb0010274

Yu, H., Chen, Z., Wan, Y., & Sun, X. (2024). Temperature-humidity-density dependent evaporation behaviour of clay and sandy clay. European Journal of Soil Science, 75(2), e13484. https://doi.org/10.1111/ejss.13484

Published

2026-06-24